Seminar: Ahmad R. Kirmani, National Institute of Standards and Technology (NIST)
Title: Exploring scalable coating of inorganic semiconductor inks: the surface structure-property-performance correlations
Abstract: Inorganic semiconductor inks – such as colloidal quantum dots (CQDs) and transition metal oxides (MOs) – can potentially enable low-cost flexible and transparent electronics via ‘roll-to-roll’ printing. Surfaces of these nanometer-sized CQDs and MO ultra-thin films lead to surface phenomenon with implications on film formation during coating, crystallinity and charge transport. In this talk, I will describe my recent efforts aimed at understanding the crucial role of surface structure in these materials using photoemission spectroscopy and X-ray scattering. Time-resolved X-ray scattering helps reveal the various stages during CQD ink-to-film transformation during blade-coating. Interesting insights include evidence of an early onset of CQD nucleation toward self-assembly and superlattice formation. I will close by discussing fresh results which suggest that nanoscale morphology significantly impacts charge transport in MO ultra-thin (≈5 nm) films. Control over crystallographic texture and film densification allows us to achieve high-performing (electron mobility ≈40 cm2V-1s-1), blade-coated MO thin-film transistors.
Bio: Dr. Ahmad R. Kirmani is a Guest Researcher in the Materials Science and Engineering Division, National Institute of Standards and Technology (NIST) in the group of Dr. Dean M. DeLongchamp and Dr. Lee J. Richter. He is exploring scalable coating of inorganic semiconductor inks using X-ray scattering. He received his PhD in Materials Science and Engineering from the King Abdullah University of Science and Technology (KAUST) under the supervision of Prof. Aram Amassian in 2017 for probing the surface structure-property relationship in colloidal quantum dot photovoltaics. He has published 30 articles in high-impact journals such Advanced Materials, ACS Energy Letters and the Nature family, and is also a volunteer science writer for the Materials Research Society (MRS) since the last couple of years and has contributed 10 news articles, opinions and perspectives.