In this project we examined the effect of size on the critical potential for porosity evolution. As size decreases, Gibbs-Thomson effects dominate and properties, such as the melting point of a particle, decrease as a function of 1/radius of the particle. Here we report the opposite: the potential required to fabricate a porous particle actually increases!
Related
- Apparent inverse Gibbs-Thomson effect in dealloyed nanoporous nanoparticles (Phys. Rev. Lett. 108, 225503, 2012)