Diverse Organic Field Effect Transistor Sensor Responses
Naphthalenetetracarboxylic diimide derivatives (octyl “8” NTCDI, dimethylaminopropyl “DMP” NTCDI), and copper phthalocyanine (CuPc) were used to form a diverse organic field-effect transistor (OFET) sensor array. CuPc and 8-NTCDI are p-channel and n-channel semiconductors respectively, showing expected and opposing responses to analytes. DMP-NTCDI, on the other hand, because of its ionizable side chain, shows response directions and magnitudes that are not correlated to those of the other two.
The result is a distinct response pattern and unambiguous recognition ability for individual analytes. The differences are even more dramatic if the time evolution of the responses is considered. The three-response patterns obtained from representative polar, nonpolar, acidic, and basic vapors were all different, showing the potential for this approach in rapid, low-cost electronic detection of volatile compounds.
- Diverse organic field-effect transistor sensor responses from two functionalized naphthalenetetracarboxylic diimides and copper phthalocyanine semiconductors distinguishable over a wide analyte range (Advanced Functional Materials, Vol. 23, Issue 33, September 6, 2013, pgs. 4094-4104)
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