{"id":45912,"date":"2024-05-23T11:19:31","date_gmt":"2024-05-23T15:19:31","guid":{"rendered":"https:\/\/engineering.jhu.edu\/materials\/?post_type=news&#038;p=45912"},"modified":"2024-05-23T11:19:31","modified_gmt":"2024-05-23T15:19:31","slug":"tunnel-vision-pays-off-for-battery-charging-breakthrough","status":"publish","type":"news","link":"https:\/\/engineering.jhu.edu\/materials\/news\/tunnel-vision-pays-off-for-battery-charging-breakthrough\/","title":{"rendered":"Tunnel Vision Pays Off for Battery-Charging Breakthrough"},"content":{"rendered":"<p><span data-contrast=\"auto\">A Johns Hopkins materials scientist was part of a team that has discovered how to make the lithium-ion batteries used in smartphones and electric vehicles charge faster and hold a charge longer.<\/span><span data-ccp-props=\"{&quot;134233117&quot;:false,&quot;134233118&quot;:false,&quot;201341983&quot;:0,&quot;335551550&quot;:1,&quot;335551620&quot;:1,&quot;335559738&quot;:0,&quot;335559739&quot;:0,&quot;335559740&quot;:279}\">\u00a0<\/span><\/p>\n<p><span data-contrast=\"auto\">\u201cWe wanted to improve the energy storage of these batteries that power everything from laptops and tablets to cars, power tools, and even backup energy systems. We figured out a way to pack the battery with more lithium ions to allow them to store more energy,\u201d said team member Yuting Luo, an assistant professor of materials science and engineering at the Whiting School of Engineering, who worked with collaborators at Texas A&amp;M University on the project. Their results appear in <\/span><a href=\"https:\/\/www.nature.com\/articles\/s41563-024-01842-y\"><span><i>Nature Materials<\/i><\/span><\/a><i><span data-contrast=\"auto\">.<\/span><\/i><span data-ccp-props=\"{&quot;134233117&quot;:false,&quot;134233118&quot;:false,&quot;201341983&quot;:0,&quot;335551550&quot;:1,&quot;335551620&quot;:1,&quot;335559738&quot;:0,&quot;335559739&quot;:0,&quot;335559740&quot;:279}\">\u00a0<\/span><\/p>\n<p><span data-contrast=\"auto\">The key is a technique called pre-intercalation, during which the researchers first insert metal ions into the battery material, opening tunnels and creating more space for ions to move around and store more energy. In addition, for this study, the team chose to work with vanadium oxide, a metal material that is not only stable but also readily available.<\/span><span data-ccp-props=\"{&quot;134233117&quot;:false,&quot;134233118&quot;:false,&quot;201341983&quot;:0,&quot;335551550&quot;:1,&quot;335551620&quot;:1,&quot;335559738&quot;:0,&quot;335559739&quot;:0,&quot;335559740&quot;:279}\">\u00a0<\/span><\/p>\n<p><span data-contrast=\"auto\">\u201cWe are searching for a cobalt substitute for battery manufacturing since cobalt is toxic to the environment and heavily relied on globally,\u201d says Luo. \u201cVanadium oxide has a high capacity for energy storage, is very thermodynamically stable, and abundant around the world. Using it can help reduce dependence on cobalt for batteries.\u201d <\/span><span data-ccp-props=\"{&quot;134233117&quot;:false,&quot;134233118&quot;:false,&quot;201341983&quot;:0,&quot;335551550&quot;:1,&quot;335551620&quot;:1,&quot;335559685&quot;:0,&quot;335559737&quot;:0,&quot;335559738&quot;:0,&quot;335559739&quot;:160,&quot;335559740&quot;:279}\">\u00a0<\/span><\/p>\n<p><span data-contrast=\"auto\">She says that V2O5 was used in this work as the active material to create a cathode, which is a positively and negatively charged electrode that allows electricity into a battery.<\/span><span data-ccp-props=\"{&quot;134233117&quot;:false,&quot;134233118&quot;:false,&quot;201341983&quot;:0,&quot;335551550&quot;:1,&quot;335551620&quot;:1,&quot;335559685&quot;:0,&quot;335559737&quot;:0,&quot;335559738&quot;:0,&quot;335559739&quot;:160,&quot;335559740&quot;:279}\">\u00a0<\/span><\/p>\n<p><span data-contrast=\"auto\">To start, the team introduced sodium and potassium into the V2O5 tunnels, forming two pre-intercalated compounds: sodium ions (NaxV2O5) and potassium ions (KxV2O5). These materials exhibit different electrochemical behaviors, including variations in their energy storage capabilities and the pathways along which the ions can move through the crystal structure. Luo and the researchers observed these distinctions by applying two experimental techniques: they examined the electrochemical reactions using a synchrotron (a powerful x-ray source), then analyzed individual crystals using specialized diffraction methods.<\/span><span data-ccp-props=\"{&quot;134233117&quot;:false,&quot;134233118&quot;:false,&quot;201341983&quot;:0,&quot;335551550&quot;:1,&quot;335551620&quot;:1,&quot;335559738&quot;:0,&quot;335559739&quot;:0,&quot;335559740&quot;:279}\">\u00a0<\/span><\/p>\n<p><span data-contrast=\"auto\">\u201cWhen lithium ions passed through the structure, we were surprised to discover that the pre-intercalated sodium ions rearranged themselves within the tunnels whereas potassium-ions retained their original positions,\u201d says Luo. \u201cOur findings show that diffusion pathways have a significant impact on electrochemical performances, offering a new approach to the design of battery materials and a new understanding of ion diffusion.\u201d <\/span><span data-ccp-props=\"{&quot;134233117&quot;:false,&quot;134233118&quot;:false,&quot;201341983&quot;:0,&quot;335551550&quot;:1,&quot;335551620&quot;:1,&quot;335559685&quot;:0,&quot;335559737&quot;:0,&quot;335559738&quot;:0,&quot;335559739&quot;:160,&quot;335559740&quot;:279}\">\u00a0<\/span><\/p>\n<p><span data-contrast=\"auto\">Luo presented her findings at the <\/span><a href=\"https:\/\/aps.anl.gov\/Users-Information\/User-Community\/Users-Meetings\"><span data-contrast=\"none\">APS and Center for Nanoscale Materials Users Meeting<\/span><\/a><span data-contrast=\"auto\"> on May 6.\u00a0 <\/span><span data-ccp-props=\"{&quot;134233117&quot;:false,&quot;134233118&quot;:false,&quot;201341983&quot;:0,&quot;335551550&quot;:1,&quot;335551620&quot;:1,&quot;335559685&quot;:0,&quot;335559737&quot;:0,&quot;335559738&quot;:0,&quot;335559739&quot;:160,&quot;335559740&quot;:279}\">\u00a0<\/span><\/p>\n","protected":false},"template":"","class_list":["post-45912","news","type-news","status-publish","hentry","news_categories-research"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v28.0 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Tunnel Vision Pays Off for Battery-Charging Breakthrough - Department of Materials Science &amp; 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